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「星間エネルギーによる非水系ペプチド形成の新たな経路」

iLIFE by iLIFE
2026年1月20日
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**ニュース概要**

生命の分子構成要素の起源は、科学における中心的な問いです。最も単純なタンパク質生成アミノ酸であるグリシンなどのいくつかのα-アミノ酸が隕石や彗星で検出されており、これは一部の前生物分子が地球外起源であることを示唆しています。しかし、ペプチド、すなわちペプチド結合で結ばれた短いα-アミノ酸の鎖の形成は、天体物理学的条件下では未解決のままでした。ここでは、液体水が存在しない状態で、イオン化放射線にさらされた星間氷の類似物の中でタンパク質の構成要素が形成されることを示します。冷却温度でプロトンで照射された同位体標識グリシンを使用し、最も単純なジペプチドであるグリシルグリシンの形成を、重水と通常の水を副産物として検出しました。ペプチド結合の形成は、赤外分光法および高解像度質量分析によって確認され、他の複雑な有機種の生成も明らかになりました。これらの発見は、宇宙のような条件下でのペプチド形成の非水性経路を示し、こうした分子が冷たい星間物質中で形成され、形成中の惑星系に取り込まれる可能性があることを示唆しています。我々の結果は、初期の生化学的進化に関する水中心のモデルに挑戦し、生命の起源に関する潜在的な設定を広げるものです。

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